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Based on results seen with molecular catalyst, we hypothesize that through using a polymeric overlayer on platinum and nickel electrodes, we will limit the rate of hydrogen evolution. To do this we will define the rate of partitioning (ip, H) and the rate of substrate transport (is, H) through the polymer. To do this we will use rotating disk voltammetry with Pt and Ni disk electrodes (RDEs) coated in a polymer with a known thickness. By altering the thickness of the polymer layer, we will alter the diffusion pathlength, lowering the is, H value for the system while keeping ip, H constant. This will allow us to model the diffusion rate of H+ as a function of diffusion path length. To define the ip, H values for each polymer, we will test the rate of H2 production in solutions with different pH values. Knowing the is, H values, we can back calculate the concentration of protons at the electrolyte-polymer interface and derive the ip, H value for that specific polymer. To further elucidate the mechanism of proton transport through the polymer membrane, we will make use of proton inventory studies which we previously used to study the proton transport mechanism in poly-4-vinyl pyridine.

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分子触媒と見の結果に基づいて、我々 はプラチナ、ニッケル電極で、高分子オーバーレイヤーによる水素発生の率に制限すること仮説します。これを行う (ip、H) のパーティション分割の割合を定義およびポリマー基板輸送 (は、H) の率。ボルタをディスク回転を用いてこれを行う

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Seen as catalysts for Platinum and nickel electrodes in we are based on the results, the hypothesis that to limit the rate of hydrogen production by polymer overlayer. (Ip, H) do define a partition ratio and polymer substrate transport (the H) of rate. Volta disc spinning

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我々 のプラチナ、ニッケル電極用触媒は、結果、水素の速度を制限する高分子による生産 overlayer 仮説に基づいているために見られます。(Ip、H) パーティションの比率およびポリマー基板 (H) の輸送率定義してください。ボルタ ディスク回転

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Our Platinum, electrode catalyst, as a result, be looking for are based on production to limit the velocity of hydrogen polymer overlayer hypothesis. (Ip, H), defined transport rate of partition ratio and polymer substrate (H). Volta disc spinning

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当社のプラチナ、電極触媒、その結果、探しているため水素高分子オーバーレイヤー仮説の速度を制限する生産に基づいています。(Ip, H) は、パーティションの比率およびポリマー基板 (H) の輸送率を定義します。ボルタ ディスク回転

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Our Platinum, electrode catalyst and as a result, based on production to limit the speed of hydrogen polymer overlayer hypothesis is looking for. (Ip, H) that defines the partition ratio of polymer substrate (H) shipping rate. Volta disc spinning

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当社のプラチナ電極の触媒を探している水素高分子オーバーレイヤー仮説の速度を制限する生産に基づく結果として。(Ip、H) ポリマー基板 (H) 送料の分配率を定義します。ボルタ ディスク回転

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As a result based on production to limit the speed of looking for our Platinum electrode catalyst hydrogen polymer overlayer hypothesis. (Ip, H) defines the ratio of polymer substrate (H) shipping. Volta disc spinning

INTO JAPANESE

結果として探している白金電極触媒水素高分子オーバーレイヤー仮説の速度を制限する生産に基づいています。(Ip, H) は、高分子基板 (H) の出荷の比率を定義します。ボルタ ディスク回転

BACK INTO ENGLISH

Based on production to limit the speed of the Platinum electrode catalyst hydrogen polymer overlayer hypothesis are looking for as a result. (Ip, H) that defines the ratio of polymer substrate (H) shipping. Volta disc spinning

INTO JAPANESE

その結果を探している白金電極触媒水素高分子オーバーレイヤー仮説の速度を制限する生産に基づきます。(Ip、H) ポリマー基板 (H) の出荷の比率を定義します。ボルタ ディスク回転

BACK INTO ENGLISH

Based on production to limit the speed of the Platinum electrode catalyst hydrogen polymer overlayer hypothesis are looking for as a result. (Ip, H) defines the ratio of polymer substrate (H) shipping. Volta disc spinning

INTO JAPANESE

その結果を探している白金電極触媒水素高分子オーバーレイヤー仮説の速度を制限する生産に基づきます。(Ip, H) は、高分子基板 (H) の出荷の比率を定義します。ボルタ ディスク回転

BACK INTO ENGLISH

Based on production to limit the speed of the Platinum electrode catalyst hydrogen polymer overlayer hypothesis are looking for as a result. (Ip, H) that defines the ratio of polymer substrate (H) shipping. Volta disc spinning

INTO JAPANESE

その結果を探している白金電極触媒水素高分子オーバーレイヤー仮説の速度を制限する生産に基づきます。(Ip、H) ポリマー基板 (H) の出荷の比率を定義します。ボルタ ディスク回転

BACK INTO ENGLISH

Based on production to limit the speed of the Platinum electrode catalyst hydrogen polymer overlayer hypothesis are looking for as a result. (Ip, H) defines the ratio of polymer substrate (H) shipping. Volta disc spinning

INTO JAPANESE

その結果を探している白金電極触媒水素高分子オーバーレイヤー仮説の速度を制限する生産に基づきます。(Ip, H) は、高分子基板 (H) の出荷の比率を定義します。ボルタ ディスク回転